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hello again. 
to answer my question, after 1' search i realized that yes, this is possible through "mapping/custom actions" and then u set the keystroke. 
now i have something else :) 
with my apple remote control i have only 6 buttons(12 held) so there are a lot of limitations. 
if i find another remote control(and is supported) with 40 keys for example, remote buddy will still support only the 12 buttons? 
i think yes/i hope not 
but plz answer. 
i have an old mac with no IRreciever so i bought the microsoft remote control and reciever and i use it with my remote control from ipod+universal dock i bought. 
but now i also have the microsoft remote control,A LOT OF KEYS. 
is there any way/remote control that remote buddy can use all of the keys?
thankz